The particle model
The particle model says that all matter is made of tiny particles that are always moving. There are forces of attraction between the particles, and the amount of space between them depends on the state. Heating gives the particles more kinetic energy, so they move faster.
| Solid | Liquid | Gas |
|---|
| Arrangement | Packed closely in a regular pattern | Close together, no regular pattern | Far apart, randomly spread out |
| Movement | Vibrate in fixed positions | Move around and slide past each other | Move quickly in all directions |
| Attraction | Strong | Weaker than in a solid | Very weak |
| Shape | Fixed shape | Takes the shape of its container | Fills its whole container |
| Volume | Fixed volume | Fixed volume | No fixed volume |
| Can it be compressed? | No (almost not at all) | Hardly at all | Yes, easily, because of the large spaces |
Changes of state
| Change | From → to | What happens to the particles |
|---|
| Melting | Solid → liquid | Heating makes particles vibrate so much they break free of their fixed positions |
| Freezing | Liquid → solid | Cooling slows the particles until attractions hold them in fixed positions |
| Evaporation | Liquid → gas (at the surface) | Faster particles at the surface escape, at temperatures below the boiling point |
| Boiling | Liquid → gas (throughout) | At the boiling point, gas bubbles form all through the liquid |
| Condensation | Gas → liquid | Cooling slows the particles so attractions pull them close together |
| Sublimation | Solid → gas | Particles escape straight from the solid without melting first |
| Deposition | Gas → solid | Gas particles join a solid directly, such as frost forming on a cold night |
Heating ice from −10 °C to 110 °C (at normal air pressure)
- From −10 °C to 0 °C the ice warms up: its particles vibrate faster.
- At 0 °C the ice melts. The temperature stays at 0 °C until all the ice has melted, because the energy is used to overcome the attractions between particles rather than to speed them up.
- From 0 °C to 100 °C the liquid water warms up.
- At 100 °C the water boils. The temperature again stays constant until all the water has become steam.
- Above 100 °C the steam (water vapor) warms up.
A common mistake is to say that particles get bigger when a substance is heated. The particles stay the same size; they move faster and spread further apart, so the substance takes up more space. This is called expansion.
More things the model explains
- Diffusion: particles spread out from where there are many of them to where there are fewer, because they move randomly. Diffusion is fastest in gases and speeds up at higher temperatures. This is why a smell spreads across a room.
- Gas pressure: gas particles constantly collide with the walls of their container. Heating a sealed container makes the particles move faster and hit the walls harder and more often, so the pressure rises.
- Dry ice: solid carbon dioxide sublimes (turns straight into a gas) at about −78 °C at normal air pressure, which is why it never leaves a puddle.
Check yourself
- Name the change of state from gas to liquid.
- Why can a gas be compressed but a solid cannot?
- While ice is melting, its temperature stays at 0 °C even though it is still being heated. Why?
- Water droplets form on the outside of a glass of iced water. Where do they come from?
- A puddle dries up on a warm day, although the water never reaches 100 °C. Explain how.
- Explain why a smell from the kitchen spreads through a house.
- A student writes: "When a metal rod is heated, its particles expand." Correct the statement.
- Give two differences between evaporation and boiling.
Answers: 1. Condensation. 2. Gas particles have large spaces between them, so they can be pushed closer together; the particles in a solid are already packed tightly. 3. The energy is being used to overcome the attractions between the particles (to break them out of their fixed positions), not to make them move faster. 4. Water vapor in the air touches the cold glass, cools down and condenses into liquid water. 5. Evaporation: some particles at the surface have enough energy to escape into the air as a gas, even below the boiling point. 6. Diffusion: the gas particles of the smell move randomly and spread out from where there are many of them to where there are fewer. 7. The particles do not expand. They vibrate faster and move further apart, so the rod expands. 8. Evaporation happens only at the surface, while boiling happens throughout the liquid (with bubbles); evaporation happens at any temperature, while boiling happens only at the boiling point.